Phosphorous-doped bimetallic sulfides embedded in heteroatom-doped carbon nanoarrays for flexible all-solid-state supercapacitors

نویسندگان

چکیده

Flexible supercapacitors (SCs) have become a popular research topic due to their extra-long service life, foldability, and wearability. Nevertheless, low energy density restricts applications. Here, we synthesized phosphorus-doped bimetallic sulfides embedded in heteroatom-doped (N, S, P) carbon shells (P-ZCS/HC) using simple approach create high-performance flexible electrodes. The three-dimensional architecture made by interlaced nanosheets was preserved, raised nanoparticles appeared on the rough surface during annealing operation, increasing specific area potential exposure electrolyte. It is noteworthy that optimal P-ZCS/HC electrode possessed remarkable capacity of 1080 C g−1 at 1 A along with superb cycling stability. These extraordinary properties were primarily caused plentiful redox reactions, enhanced conductivity, synergic effects P-doped metal shells. Density functional theory simulations confirmed good function electrodes ability boost improve reactive dynamics, promote OH− adsorption. Notably, assembled all-solid-state hybrid SC exhibited maximum 62.9 W h kg−1 power 16 kW kg−1, while being able maintain 92.0% its initial after 10,000 cycles. This systematic report provides new insight into design synthesis complex components outstanding structures for field.

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ژورنال

عنوان ژورنال: Science China. Materials

سال: 2021

ISSN: ['2095-8226', '2199-4501']

DOI: https://doi.org/10.1007/s40843-020-1667-1